Sodium Metabisulfite

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Sodium Metabisulfite (Na2S2O5) is an inorganic compound widely utilized in the skincare and cosmetic industry for its preservative and antioxidant properties. This white or yellowish-white crystalline powder plays a crucial role in maintaining the integrity, stability, and safety of skincare products.

In skincare formulations, Sodium Metabisulfite functions primarily as an antioxidant, helping to protect the products from oxidation, which can cause deterioration of active ingredients, discoloration, and a reduction in product effectiveness. By preventing these oxidative processes, Sodium Metabisulfite extends the shelf life of products and ensures that their beneficial properties remain potent and effective over time.

Additionally, as a preservative, it helps to inhibit the growth of microbes and bacteria in products, especially those containing water. This is essential for ensuring the safety and hygiene of skincare products, as microbial contamination can lead to skin irritations, infections, and spoilage of the product. Sodium Metabisulfite’s role in preventing microbial growth makes it a valuable ingredient in creams, lotions, serums, and other personal care items.

Despite its beneficial uses in skincare formulations, Sodium Metabisulfite can be a concern for individuals with sensitive skin or sulfite allergies. In some cases, it may cause allergic reactions or skin irritation, particularly in those who are sensitive to sulfites. Therefore, its inclusion in skincare products is carefully regulated and monitored to ensure safe concentration levels that are unlikely to cause adverse reactions in most users.

Manufacturers and formulators of skincare products are also required to list Sodium Metabisulfite on product labels, allowing consumers to make informed choices, especially those with known sensitivities. As with any skincare ingredient, it is recommended to perform a patch test before using a new product extensively, particularly if you have sensitive skin or allergies.

In summary, Sodium Metabisulfite is a key ingredient in the skincare industry, valued for its antioxidant and preservative qualities that help enhance product stability, longevity, and safety. Its careful use within regulated limits ensures that skincare products remain effective and safe for a wide audience, while mindful consideration is given to those with specific sensitivities.

Sodium metabisulfite or sodium pyrosulfite (IUPAC spelling; Br. E. sodium metabisulphite or sodium pyrosulphite) is an inorganic compound of chemical formula Na2S2O5. The substance is sometimes referred to as disodium metabisulfite. It is used as a disinfectant, antioxidant, and preservative agent. When dissolved in water it forms sodium bisulfite.

Sodium metabisulfite
Sodium metabisulfite
Structure of sodium metabisulfite
Names
Other names
Sodium pyrosulfite
Sodium disulfite
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ECHA InfoCard 100.028.794 Edit this at Wikidata
EC Number
  • 231-673-0
E number E223 (preservatives)
RTECS number
  • UX8225000
UNII
  • InChI=1S/2Na.H2O5S2/c;;1-6(2)7(3,4)5/h;;(H,1,2)(H,3,4,5)/q2*+1;/p-2
  • [O-]S(=O)S(=O)(=O)[O-].[Na+].[Na+]
Properties
Na2S2O5
Molar mass 190.107 g/mol
Appearance White to yellow powder
Odor Faint SO2
Density 1.48 g/cm3
Melting point 170 °C (338 °F; 443 K) decomposition begins at 150 °C
  • 45.1 g/100mL (0 °C)
  • 65.3 g/100mL (20 °C)
  • 81.7 g100 mL (100 °C)
Solubility Very soluble in glycerol
Slightly soluble in ethanol
Hazards
GHS labelling:
GHS05: CorrosiveGHS07: Exclamation mark
Danger
H302, H318
P264, P270, P280, P301+P312, P305+P351+P338, P310, P330, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
2
0
1
NIOSH (US health exposure limits):
PEL (Permissible)
None
REL (Recommended)
TWA 5 mg/m3
IDLH (Immediate danger)
N.D.
Safety data sheet (SDS) Mallinckrodt MSDS
Related compounds
Other anions
Sodium sulfite
Sodium bisulfite
Other cations
Potassium metabisulfite
Related compounds
Sodium dithionite
Sodium thiosulfate
Sodium sulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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